The opening phase of the 2025/26 Champions League reaches the halfway stage during the first week in November.
Matchday 4 features several eye-catching fixtures. Moreover, many of these games could have a significant bearing on the race to progress to the last 16.
Read on as we look at the latest Champions League betting odds. We will also preview what promises to be a thrilling fourth round of matches.
Champions League 2025/26 – Betting
Leading online sportsbook Betway rates reigning champions Paris Saint-Germain as the favourites to retain the title.
However, several European giants remain close behind in the outright market.
Champions League outright betting
- Paris Saint-Germain – 9/2
- Arsenal – 5/1
- Barcelona – 11/2
- Liverpool – 7/1
- Bayern Munich – 15/2
- Real Madrid – 9/1
- Manchester City – 10/1
- Chelsea – 20/1
- Inter Milan – 28/1
- Newcastle United – 28/1
- Tottenham Hotspur – 40/1
- Borussia Dortmund – 50/1
- Napoli – 50/1
- Atletico Madrid – 50/1
- Juventus – 100/1
- Galatasaray – 125/1
- Atalanta – 150/1
- Athletic Club – 150/1
- Bayer Leverkusen – 150/1
- Marseille – 150/1
- Monaco – 150/1
- PSV Eindhoven – 150/1
- Eintracht Frankfurt – 200/1
- Sporting CP – 200/1
- Villarreal – 250/1
- Club Brugge – 400/1
- Ajax – 500/1
- Benfica – 500/1
- Olympiakos – 500/1
- Bodo/Glimt – 1000/1
- FC Copenhagen – 1000/1
- FK Qarabag – 1000/1
- Pafos FC – 1000/1
- Slavia Prague – 1000/1
- Union Saint-Gilloise – 1000/1
- Kairat Almaty – 2000/1
Champions League 2025/26 Matchday 4 Preview
Matchday 4 brings several important fixtures across Tuesday and Wednesday.
Tuesday, November 4
- Slavia Prague vs Arsenal
- Napoli vs Eintracht Frankfurt
- Atletico Madrid vs Union Saint-Gilloise
- Bodo/Glimt vs Monaco
- Juventus vs Sporting CP
- Liverpool vs Real Madrid
- Olympiacos vs PSV Eindhoven
- Paris Saint-Germain vs Bayern Munich
- Tottenham Hotspur vs FC Copenhagen
